Wednesday, January 16, 2013

Devonian Black Shale as a Possible Pipeline Corrosion Issue



Warren Anderson gave me permission to post this email on this blog.  I have no comment on this and you can contact Mr. Anderson as this name below has a hyperlink to his email address.   If any desire to comment on this issue to me; I am interested in hearing what you have to say about this.



Mr. Hodgman,

I saw your corrosion control engineer blog and wanted to make contact concerning some pipeline corrosion issues we have in Kentucky.  I am a research scientist and geochemist at the University of Kentucky and saw that you had an interest in this area of pipeline corrosion that I have done some research in. 

I have done some preliminary work in the Devonian Black Shales in Kentucky where about 30-40 % of pipeline failures in our state have occurred when the pipeline is sited in the Black Shale.  There are geochemical reasons for this, the shale contains pyrite, an iron sulfide which oxides and forms a mild sulfuric acid, lowering the pH of groundwater and accelerating the corrosion of any steel pipelines.  The Beaumont, Ky pipeline disaster noted this in the NTSB reports.   Building anything in organic black shales is troubling, but pipelines have the potential for catastrophic events, so I have been trying to get some  research funding to study this problem..

If you know anyone in the eastern US who has pipelines in black shales please pass this message on to them.  I have a report out on some severe foundation problems (heaving) in the black shales, http://kgs.uky.edu/kgsweb/olops/pub/kgs/ri18_12.pdf,  which would also extend to pipelines.

Good blog, Keep up the good work.

Beaumont & Lancaster Kentucky Natural Gas Pipeline Ruptures

This will be a posting that will take awhile to finish.  This is the first draft.

This twin pipeline rupture in Kentucky had a major impact on pipeline corrosion control in the USA.

The major impact was a realization of the limitations of cathodic protection due to shielding issues that existed as a cause in both ruptures. Beaumont rupture was due to a highway casing shielding cathodic protection current.  This caused government regulators to demand that the pipeline operator run smart pigs in Kentucky to verify the intregity of the pipeline as this was the only method of verifying that other cased pipeline crossings didn't have serious corrosion damage.  This caused the start of the transfer of pipeline integrity budgets from CIS (Close Interval Survey) to upgrading of pipelines to run smart pigs and the running of smart pigs.  Cathodic protection staff tended to  considered the smart pigs to be experimental devices of questionable value, but government regulatory staff viewed smart pigs as the future of pipeline integrity and some pipeline operators who has experimented with smart pigs agreed.  Smart pigs at that time were low resolution and not as accurate at sizing corrosion pitting as present day tools.  The lack of accuracy in sizing corrosion pitting and claims that CIS was sufficient was the argument used by pipeline operators who were not impressed with smart pigs prior to the Beaumont incident.

Lancaster pipeline rupture occurred about a year later and resulted in more government regulations related to smart pigging since this rupture should not have happened. Once again the corrosion damage that caused the pipeline rupture was due to shielding of cathodic protection, but this time it was a rock in contact with the bottom of the pipe.  A smart pig had found the significant corrosion damage and the pipe was incompletely inspected because of the rock.  Two pipe inspectors couldn't agree on the seriousness of the corrosion damage due to the rock the pipe was in contact and no attempt was made to expose sufficient pipe to raise the pipe off the rock so that a complete inspection could be made.  the pipe was recoated as best as possible with a rock in contact with the pipe and buried.   Later the pipeline ruptured and the pipeline operator had to explain how corrosion damage not detected by CIS but found by a smart pig and incompletely inspected had failed.  Operator error, improper training of pipe inspection personnel, and sloppy pipeline integrity procedures was blamed as the cause of the rupture but smart pigs proved to be accurate in finding serious corrosion damage that previous CIS had failed to find due to a rock shielding Cathodic protection current.

Both incidents proved the value of smart pigs and the limitations of CIS.  In the NTSB report which covered both failures, CIS was clearly documented to be detective in finding serious corrosion damage if shielding issues existed.  Smart pigging was promoted as a solution to the limitations of CIS.  In addition NTSB did a survey of Kentucky pipeline operators as to how common natural gas pipeline ruptures due to external corrosion occurred.  All natural pipeline operators reported that ruptures due to external corrosion damage were rare.

The tendency of cathodic protection companies is to assume that a major news making event such as a natural gas pipeline rupture due to external corrosion will result in more business for them.  Typically the news story on a natural gas failure is that the pipeline operator had not upgraded the pipeline for the running of smart pigs and if the operator had run a smart pig the failure should not have happened.  Typically cathodic protection budgets are not increased for the doing of CIS after a major pipeline failure due to external corrosion; but smart pig budgets are increased for the modification of pipelines to run smart pigs.  The recent West Virginia natural gas rupture due to external corrosion is yet another example of if the pipeline operator had only upgraded the pipeline for running a smart pigs this could have been prevented.  If the salespersons marketing CIS have not noted the news stories on the recent external corrosion rupture that sound like all newspapers are marketing smart pigs without a sales commission; they are in a state of denial of reality.   

Saturday, January 5, 2013

Corrective Action Order to Florida Gas Transmission LLC

PHMSA/OPS has issued a corrective action order to Florida Gas Transmission LLC which can be viewed here.

Final Order for Texas Gas Transmission LLC

PHMSA/OPS has issued the final order for Texas Gas Transmision LLC, a subsidiary of Boardwalk Pipeline Partners, LP.  One of the fines was for failure to check for internal corrosion when pipe was removed during maintenace operations.  The final order can be viewed here.

Tuesday, December 25, 2012

Rate of Natural Gas Transmission Pipeline Ruptures Due to External Corrosion in the USA

It was my memory that it had been decades since a natural gas pipeline had ruptured due to external corrosion.  To verify I reviewed a listing of pipeline failures in the USA and found what appears to have been the last documented pipeline corrosion related rupture.


  • 1985 A 30 inch diameter gas pipeline operating at about 960 psi, weakened by atmospheric corrosion, ruptured, and tore out about 29 feet (8.8 m) of the carrier pipe, blew apart about 16 feet (4.9 m) of a 36-inch-diameter casing pipe, blasted an opening across Kentucky State Highway 90, and cut out a pear-shaped crater approximately 90 feet (27 m) long, 38 feet (12 m) wide, and 12 feet (3.7 m) deep near Beaumont, Kentucky. 5 people were killed in one home, and 3 injured. The fireball from the incident could be seen 20 miles away.(April 27, 1985)
 
  • 1986 A 30 inch gas pipeline ruptured due to corrosion near Lancaster, Kentucky. 3 people had serious burns, and 5 others had lesser injuries. External corrosion made worse by difficulties of Cathodic protection in rocky soil was the cause. (February 21, 1986)
 
It has been over 26 years since a natural gas transmission pipeline has had a rupture due to external corrosion.  The most recent external corrosion ruptures were both in Kentucky.  The Beaumont Kentucky rupture was due to atmospheric corrosion inside a road casing under Kentucky State Highway 90 and the Lancaster Kentucy failure was on buried pipe that was insufficiently protected by cathodic protection.  Cathodic protection cannot prevent atmospheric corrosion inside a road casing.

Monday, December 24, 2012

The Pipeline Integrity Repairs that Never Make National News

While I was working as Corrosion Specialist for a natural gas transmission pipeline, an emergency repair situation was found by a ILI tool inside a state highway casing next to a large farm house.  The high pressure natural gas pipeline had a farm tap that supplied gas to the farm house.  The pipeline passed through the front yard of the farm house and it was under the  driveway to the house.  The wall thinnnig reported by the ILI tool was significant enough that a rupture of the pipeline  inside the casing was possible.  The farm house was so close to the casing with the thin wall pipe that a rupture may have destroyed the farm house.
 
It became necessary to put the farm house family in a hotel while the replacement of the carrier pipe was being done as large pipeline construction equipment would be working in the house's front yard plus there would be no driveway.  When the pipeline crew was close to pulling the carrier pipe out of the casing, the farmer's family arrived to find out how much longer they would have to live in a hotel.   The farmer and his wife was talking to the pipeline foreman next to the highway and a little girl with her cute little dog was running around looking at all of the pipeline construction equipment.  Several of the pipeline crew had suddenly the job of watching a little girl to make sure that she didn't get too close to something that could get her hurt.   The girl and dog put the construction work on hold until she got back into the car with her parents and drove away to the hotel. 
 
The bad pipe was pulled from the casing and the new replacement pipe installed.  The pipeline was put back in service, the farm house driveway repaired, and the family moved back into their beautiful farm house.  Since this was not a Sissonville WV like event where a rupture occurred that destroyed houses and damaged a major highway,  it didn't make the national news.  However, it happened even if it didn't make the news.  For every natural gas pipeline rupture that occurres that makes the national news; there are many pipeline integrity repairs done that never makes the news. 

Saturday, December 22, 2012

Sissonville WV Natural Gas Pipeline Rupture, Explosion, & Fire

 
Some generalized statements on the Sissonville WV pipeline failure since the investigation by the NTSB (National Transportation Safety Board) is still on-going and insufficient information has been released for factual statements.

Other than SCC (stress corrosion cracking) and internal corrosion ruptures of pipelines; it has been a long time since typical external corrosion has caused a pipeline rupture.  Pipeline coatings, cathodic protection, CIS (Close Interval Survey), gas leak surveys, and ILI (inline inspection) has been very effective in almost totally eliminating typical external corrosion as a cause of pipeline ruptures.  Therefore the news release from NTSB that this pipeline rupture was due to typical external corrosion and not SCC, Pre-1970 ERW pipe seam fatigue failure, or internal corrosion was a surprise. Most consider typical external corrosion now days to be only the cause of leaks.

Pipeline ruptures due to external corrosion outside of pipe seams are now rare. For a rupture to occur the corrosion pitting has to be both deep and long. Deep Corrosion pitting of short length will result only in a gas leak which is typically found by dead plants over the pipeline or a gas leak survey. Typically the pipe coating will limit the length of corrosion pitting to a size that only results in a gas leak. 

Only if there is a significant coating failure will corrosion pitting be capable of having sufficient length with deep pitting to result in a pipeline rupture. ILI (Inline Inspection) tools care capable of finding corrosion pitting before a gas leak or pipeline rupture occur, but not all pipelines are designed for the passage of an ILI tool. Information released so far indicates that the pipeline that failed had not been upgraded for the passage of an ILI tool. 

The following is required for upgrading a pipeline built before federal minimum pipeline safety rules required that all new pipelines be designed for the passage of ILI tools: 
  • replace  mainline gate valves with full opening ball valves that allow the passage of a ILI tool
  • replace pipeline bends that are too short radius for the passage of ILI tools
  • replace unbarred tees with barred tees that may not allow the passage of ILI tools
  • remove any known pipeline feature that may damage or not allow the passage of an ILI tool
  • run a caliper, plate tool, or geometry tool that will verify the pipeline is ready for the running of an ILI metal loss tool or find features that need to removed before running a ILI metal loss tool
For pipelines that cannot be inspected by ILI tools, ECDA (External Corrosion Direct Accessment) with ICDA (Internal Corrosion Direct Assessment) is performed.  Since the pipeline that failed was downstream of a gas storage field, odds are an internal corrosion threat existed on the pipeline that would have required ICDA.  The pipeline per news releases had a ERW (electric resistance weld) seam which would have been a pre-1970 ERW seam per the construction date of this segment of the pipeline.  Since this type of seam has had service issues due to quality control issues during manufacturing, the pipeline would have had a manufacturing defect threat which would require evaluation to determine if this threat was stable or not stable.  Typically, manufacturing defects like Pre-1970 pipe seams are stable and the rupture of this pipeline was outside of the ERW seam.

Per the NTSB investigation so far, the failure was due to external corrosion on the bottom of the pipe that resulted in significant wall thinning.  The wall thinning was described as being approximately 6 feet long with as much as 70% wall thickness reduction is some locations.  Wall thinning of this length and depth is sufficient to result in a rupture of the pipeline.  There has been nothing stated to date that internal corrosion on the bottom of the pipe may have contributed to the wall thinning that resulted in a rupture of the pipe.

External corrosion does favor the bottom of the pipe due to a oxygen concentration cell effect that makes the pipe bottom anodic to the rest of the pipe surface.  The bottom of the pipe has less oxygen in the soil next to the pipe surface.  This corrosion cell can result in deep corrosion pitting which on large diameter pipelines may not be detected by over-the-line-survey CIS (Close Interval Survey) as such surveys record an average pipe-to-soil potential of the pipe surface and not the lowest pipe-to-soil potential on the pipe surface.  In addition, over the line surveys tend to not detect corrosion cells on the bottom of the pipe as effectively as corrosion cells are top of the pipe.  Corrosion cell activity under disbonded coatings can decrease the effectiveness of over-the-line surveys in detecting possible corrosion activity.    MIC (microbiologically influenced corrosion) may accelerate the oxygen concentration cell corrosion cell activity by deplorizing the pipe surface, increasing the amount of cathodic protection current required to create a polarized pipe surface at coating holidays, and requiring an increase in the cathodic protection criterion to a value greater than -850 mV.  From photos of the failure site, MIC probably was not a contributing factor in the pipeline failure but cannot be totally ruled out.

ACVG (Alternating Current Voltage Gradient) and DCVG (Direct Current Voltage Gradient) pipe coating surveys may sometimes detect coating damage on the bottom of a large diameter pipeline that a typical CIS inspection may miss due to the average pipe-to-soil potential effect.  All methods of finding coating damage that may result in corrosion damage to the pipeline have limited effectiveness if the pipe coating has significant disbondment to the pipe surface with trapped water and few coating holidays.  All pipeline coating surveys tend to detect coating holidays more effectively than disbonded coating.   The best way of detecting disbonded pipe coating is a ILI EMAT tool.

The photos of the failure site suggests that the backfill around the pipe that failed may have had sufficient rock and stone to damage coal tar and asphalt pipe coatings used at the time the pipeline was built. The amount of clean backfill placed around the pipe during construction would influence how much coating damage may have occurred during backfilling.  Cold Applied Tapes were not in much use when the pipeline was built and probably was not the coating system applied to the pipe.  Asphalt pipe coatings were popular during the period the pipeline was built and tend to have coating disbondment issues which may result in shielded corrosion cell activity.  At this time the pipe coating system on the pipeline that failed has not been stated.  The condition of the pipe coating where the failure occurred will be impossible to know absolutely as the explosion and fire totally destroyed it; but the condition of the pipe coating near the failure may give some indication.  The amount of corrosion damage to the pipe joint(s) that failed will give some idea of coating condition too.

Highway salts used to melt ice can cause chloride concentration to increase in the soil near the highway resulting in accelerated corrosion of buried steel.  Since the failure was near a major highway, this may have been a contributing factor.

The casing under the highway if shorted to the carrier pipe may have caused a depression of cathodic protection levels on the pipe that failed.  The electrical isolation of the casing to the carrier pipe is presently unknown.  Casing use started due to the oxygen concentration corrosion cell effect of the pipe under the highway being more anodic than pipe by the highway.  Corrosion failures under highways and railroad crossing caused the requirement of cased pipeline crossings of roads and railroads.  Modern construction practice is to use a high performance coating system for the pipe under the highway or railroad and eliminate the use of casings.  In addition, pipeline crossings under railroads and highways are done deeper by directional boring which isolates the pipeline from stresses caused by railroad traffic sufficiently to eliminate the need for a casing for load shielding of the carrier pipe.   

Desire to declare that I have not worked for Columbia Gas Transmission, but I did interview for the position of Corrosion Engineer in their Charleston, WV office.  Discussed corrosion issues with Columbia Gas Transmission staff during the Purdue Corrosion Short Course and NACE International technical committee meetings.  Consider their corrosion issues to be not unique to those I had to deal with during my career with other natural gas transmission companies.